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Generation of particle-stabilized emulsions in a microfluidic chip

Research Area: Microfluidics, nanotechnology

Supervisors: Dr Catherine Whitby and Dr Craig Priest

Description: Microfluidic technologies are challenging our conventional views of fluid processing. Microscopic droplets have become the vessel of choice for nanolitre-scale reactions, high speed analysis, and efficient separations.[1-3] Emulsion stability is crucial to a wide variety of commercial applications, including food processing, composite materials, cosmetics, and explosives. The stability of conventional emulsions is largely determined by the surfactant present at the liquid-liquid interface; however, nanoparticles may also be used to generate “particle-stabilized emulsions” with superior stability against coalescence.[4-6] In this project, particle-stabilized emulsions will be generated in microfluidic channels and their stability will be determined by inducing controlled collisions at microfluidic junctions.

References
1. Evans H. M., Surenjav E., Priest C., Herminghaus S., Seemann R., Pfohl T., In situ formation, manipulation, and imaging of droplet-encapsulated fibrin networks, Lab on a Chip 9, 1933 (2009).
2. Priest C., Quinn A., Postma A., Zelikin A.N., Ralston J., Caruso F., Microfluidic polymer multilayer adsorption on liquid crystal droplets for microcapsule synthesis, Lab on a Chip 8, 2182 (2008).
3. Priest C., Herminghaus S., Seemann R., Controlled electrocoalescence in microchannels: Targeting a single lamella, Applied Physics Letters 89, 134101 (2006).
4. Binks, B. P., Particles as surfactants-similiarities and differences, Current Opinion in Colloid and Interface Science 7, 21 (2001).
5. Binks, B. P., Whitby, C. P., Silica Particle-stabilised emulsions of silicone oil and water: aspects of emulsification, Langmuir 20, 1130 (2004).
6. Whitby, C. P., Fornasiero, D., Ralston, J., Effect of oil soluble surfactant on emulsions stabilised by clay particles, Journal of Colloid and Interface Science 323, 410 (2008).

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